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Dimethyldioxirane hydroxylation of a hypersensitive radical probe: Supporting evidence for an oxene insertion pathway

1998; Elsevier BV; Volume: 39; Issue: 45 Linguagem: Inglês

10.1016/s0040-4039(98)01871-1

1873-3581

Pavel A. Simakov, Seung‐Yong Choi, Martin Newcomb,

Chemical Reaction Mechanisms

Dimethyldioxirane oxidation of the hypersensitive radical probe (rans-2-phenylcyclopropyl)ethane gave non-rearranged hydroxylation products consistent with an oxene insertion mechanism for the reaction.