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Artigo Revisado por pares
BIBTEX RIS

Rhenium-Catalyzed Regioselective Alkylation of Phenols

2009; American Chemical Society; Volume: 131; Issue: 29 Linguagem: Inglês

10.1021/ja904360k

ISSN

1943-2984

Autores

Yoichiro Kuninobu, Takashi Matsuki, Kazuhiko Takai,

Tópico(s)

Catalytic C–H Functionalization Methods

Resumo

Treatment of phenol derivatives with terminal alkenes in the presence of a catalytic amount of a rhenium complex, Re2(CO)10, gave monoalkylated phenol derivatives in good to excellent yields. This reaction proceeds at the ortho- or para-position of phenols regioselectively.

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