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The structure of dichlorobis[μ-(3-dimethylamino-1-propanethiolato)-μ-S,N]-dipalladium(II), (I) [Pd2(C5H12NS)2Cl2], and ac,bd,eg, fh-tetrakis[μ-(3-piperidinemethanethiolato)-μ-S,N]-tripalladium(II) dichloride dihydrate, (II) [Pd3(C6H12NS)4]Cl2.2H2O

1983; Wiley; Volume: 39; Issue: 12 Linguagem: Inglês

10.1107/s0108270183009622

ISSN

1600-5759

Autores

Xavier Soláns, M. Font-Altaba, J. L. Briansó, J. Ribas, Joan Suades, Heribert Barrera,

Tópico(s)

Crystal structures of chemical compounds

Resumo

7.207 (2), b = 20.616(4), c= 5.854 (1) A, fl= 96.05 (I) °, V= 864.9 (6) A 3, Z = 2, Ox= 2.00 Mg m -3, Mo K~t, 2 = 0.71069,4,, p = 2.553 mm -~, F(000) = 512, 298 K, R =0.060 for 1492 reflections.(II): Mr-947.07,triclinic, Pi, a = 12.666 (7), b---10.595(6), c= 6.572 (5) A, a= 98.30 (2), fl---97.04(2), y= 99.84 (2) °, V= 850(2)/~ 3, Z----1, Dx= 1.85 Mgm -3, MoK~ 2= 0.71069 A, /z = 1.958 mm -~, F(000) = 490, 298 K, R = 0.071 for 1879 reflections.(I) was solved by direct methods, using MULTAN and DIRDIF, (II) by the heavy-atom method.The four-membered Pd, S, Pd, S rings have a syn-exo conformation, with dihedral angles between the S, Pd, S planes of 154.4 (2) and 133.0 (3) ° for (I) and (II), respectively.

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