Electrically conductive in situ microfibrillar composite with a selective carbon black distribution: An unusual resistivity–temperature behavior upon cooling
2008; Elsevier BV; Volume: 49; Issue: 4 Linguagem: Inglês
10.1016/j.polymer.2007.12.043
ISSN1873-2291
AutoresKun Dai, Zhong‐Ming Li, Xiang‐Bin Xu,
Tópico(s)Smart Materials for Construction
ResumoCarbon black (CB) filled electrically conductive in situ microfibrillar poly(ethylene terephthalate) (PET)/polyethylene (PE) composites (FCMC) with CB particles selectively localizing at the surfaces of PET microfibrils were successfully prepared through a slit die extrusion–hot stretch–quenching process. Resistivity–temperature behaviors of the FCMC samples were studied systematically during heating–cooling runs (HCR) with different top test temperatures. When the top test temperature was set as 140 °C, the resistivity abnormally increased during cooling below 100 °C, showing the cooling-induced resistivity increase. The room-temperature resistivity after one heating–cooling run was 4 orders of magnitude higher than that of the original samples. Thermal residual stresses developed in the interfaces between PET microfibrils and PE matrix were responsible for the cooling-induced resistivity increase, which led to the damage of the conductive network. The top test temperature dominated the cooling-induced resistivity increase of FCMC. There was a critical temperature, 150 °C, above which the cooling-induced resistivity increase disappeared. A model was proposed to illustrate this cooling-induced resistivity increase.
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