Lewis Acid Catalyzed Reaction of o -[1-(Alkylthio)alkyl]phenols: The Generation and Reaction of o -Quinonemethides and Applications to Cannabinoid Synthesis
1990; Oxford University Press; Volume: 63; Issue: 6 Linguagem: Inglês
10.1246/bcsj.63.1647
ISSN1348-0634
AutoresTsutomu Inoue, Seiichi Inoue, Kikumasa Sato,
Tópico(s)Synthesis of Organic Compounds
ResumoAbstract o-Quinonemethides were prepared by treating o-[1-(alkylthio)alkyl]phenols with a Lewis acid. The Diels–Alder reaction of the resulting o-quinonemethides was also catalyzed by the Lewis acid. Hexahydrocanna-binol was synthesized according to this method.
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