Miscibility of C60-end-capped poly(ethylene oxide) with poly(p-vinylphenol)
2000; Wiley; Volume: 201; Issue: 18 Linguagem: Inglês
10.1002/1521-3935(20001201)201
ISSN1521-3935
AutoresXu-Dong Huang, S. H. Goh, Swee Yong Lee,
Tópico(s)Graphene research and applications
ResumoMacromolecular Chemistry and PhysicsVolume 201, Issue 18 p. 2660-2665 Research Article Miscibility of C60-end-capped poly(ethylene oxide) with poly(p-vinylphenol) Xu-Dong Huang, Xu-Dong Huang Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543Search for more papers by this authorSuat Hong Goh, Suat Hong Goh chmgohsh@nus.edu.sg Search for more papers by this authorSwee Yong Lee, Swee Yong Lee Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543Search for more papers by this author Xu-Dong Huang, Xu-Dong Huang Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543Search for more papers by this authorSuat Hong Goh, Suat Hong Goh chmgohsh@nus.edu.sg Search for more papers by this authorSwee Yong Lee, Swee Yong Lee Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543Search for more papers by this author First published: 03 January 2001 https://doi.org/10.1002/1521-3935(20001201)201:18 3.0.CO;2-8Citations: 52AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract A fullerene (C60)-end-capped poly(ethylene oxide) (FPEO) has been prepared by the cycloaddition reaction of monoazido-terminated poly(ethylene oxide) with C60. The majority of the FPEO sample is the monoadduct as shown by thermogravimetry and X-ray photoelectron spectroscopy. Most electronic characteristics of C60 are retained in the polymer as shown by its UV-visible absorption spectrum. The incorporation of C60 reduces the extent of crystallinity of PEO by 17%. The miscibility behavior of FPEO with poly(p-vinylphenol) (PVPh) was studied. Similar to PEO, FPEO is miscible with PVPh over the entire composition range. The hydrogen-bonding interaction between FPEO and PVPh is as strong as that between PEO and PVPh as shown by Fourier-transform infrared spectroscopy. Citing Literature Volume201, Issue18December 2000Pages 2660-2665 RelatedInformation
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