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Epoxidation of α,β-unsaturated ketones with sodium perborate

1995; Elsevier BV; Volume: 36; Issue: 5 Linguagem: Inglês

10.1016/0040-4039(94)02346-d

1873-3581

Thomas Straub,

Sulfur-Based Synthesis Techniques

α,β-Unsaturated ketones are rapidly converted to epoxyketones at room temperature in aqueous sodium perborate in the presence of a phase transfer catalyst. Organic solvents can be used to modify the rate of epoxidation.