Darstellung, Konfigurationen und NMR‐Daten der Säuren CH 3 (SR) CHCOOH (R C 6 H 5 , CH 2 C 6 H 5 , CH 2 COOH)
1978; Wiley; Volume: 320; Issue: 3 Linguagem: Inglês
10.1002/prac.19783200302
ISSN0021-8383
Autores Tópico(s)Chemical Synthesis and Analysis
ResumoPreparation, Configurations and N.M.R. Dates of the Acids CH 3 (SR)CHCOOH (R C 6 H 5 , CH 2 C 6 H 5 , CH 2 COOH) The cis and trans isomers of the acids CH 3 (SR)CHCOOH (R C 6 H 5 , CH 2 C 6 H 5 , CH 2 COOH) were prepared by addition of HSR to CH 3 CCCOOH in alkaline water solution and by alkaline hydrolysis of CH 3 C(SR) 2 CH 2 COOC 2 H 5 (R C 6 H 5 , CH 2 C 6 H 5 , CH 2 COOC 2 H 5 ). The oxidation products CH 3 C(SO 2 R) CHCOOH (R C 6 H 5 , CH 2 COOH) were also prepared. The n.m.r. dates of the acids were obtained and some relations between them were discussed.
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