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Ash from a pulp mill boiler—Characterisation and vitrification

2010; Elsevier BV; Volume: 179; Issue: 1-3 Linguagem: Inglês

10.1016/j.jhazmat.2010.03.004

1873-3336

Ana Sebastiana Monteiro Ribeiro, Regina da Conceição Corredeira Monteiro, E.J.C. Davim, M.H.V. Fernandes,

Pigment Synthesis and Properties

The physical, chemical and mineralogical characterisation of the ash resulting from a pulp mill boiler was performed in order to investigate the valorisation of this waste material through the production of added-value glassy materials. The ash had a particle size distribution in the range 0.06–53 μm, and a high amount of SiO2 (∼82 wt%), which was present as quartz. To favour the vitrification of the ash and to obtain a melt with an adequate viscosity to cast into a mould, different amounts of Na2O were added to act as fluxing agent. A batch with 80 wt% waste load melted at 1350 °C resulting in a homogeneous transparent green-coloured glass with good workability. The characterisation of the produced glass by differential thermal analysis and dilatometry showed that this glass presents a stable thermal behaviour. Standard leaching tests revealed that the concentration of heavy metals in the leaching solution was lower than those allowed by the Normative. As a conclusion, by vitrification of batch compositions with adequate waste load and additive content it is possible to produce an ash-based glass that may be used in similar applications as a conventional silicate glass inclusively as a building ecomaterial.