Preparation and reactivity of some functionalized halomethylzinc carbenoids
1999; Elsevier BV; Volume: 40; Issue: 1 Linguagem: Inglês
10.1016/s0040-4039(98)80012-9
ISSN1873-3581
AutoresA. B. Charette, André M. Beauchemin, Jean-François Marcoux,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoVarious mixed diorganozinc reagents were prepared by the irradiation of diethylzinc and functionalized alkyl iodides. These species were shown to react with dihalomethane to form zinc carbenoids in a highly regioselective manner. In some cases, the latter reagents proved to be effective cyclopropanating reagents.
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