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ESR spectra of the Cu2+, Ag2+, and Au2+ ions

1989; Elsevier BV; Volume: 162; Issue: 6 Linguagem: Inglês

10.1016/0009-2614(89)87004-6

1873-4448

R. J. Van Zee, W. Weltner,

Molecular Spectroscopy and Structure

Cu2+, Ag2+, and Au2+ in their 2Σg+ ground states have been observed in solid neon matrices at 4 K via X-band electron-spin-resonance (ESR) spectroscopy. The g and hyperfine tensor components of each cation have been interpreted in terms of the orbital characteristics of the unpaired electron.