Formation and X-ray crystal structure of an A-frame µ-methylene diplatinum complex containing bridging cyclometallated 1,2-bis(diphenylphosphino)ethane
1983; Royal Society of Chemistry; Issue: 1 Linguagem: Inglês
10.1039/c39830000034
ISSN2050-5639
AutoresDennis P. Arnold, Martin A. Bennett, George M. McLaughlin, Glen B. Robertson,
Tópico(s)Asymmetric Hydrogenation and Catalysis
ResumoThe 1 : 1 adduct of the PtI–PtI dimer [Pt-µ-{o-C6H4P(Ph)CH2 CH2PPh2}]2 with methyl iodide is deprotonated by sodium methoxide to give a µ-methylenediplatinum(II) complex [Pt2-µ-{o-C6H4P(Ph)CH2CH2PPh2}2(µ-CH2)], characterised by single-crystal X-ray structural analysis; the latter complex reacts with [Me3O]PF6 to give an ethyldiplatinum(II) cation which retains the bridging cyclometallated dppe ligands.
Referência(s)