Self-assembly of 3-D 4d–4f coordination frameworks based on pyridine-3,5-dicarboxylic acid: Syntheses, crystal structures and luminescence
2010; Elsevier BV; Volume: 363; Issue: 14 Linguagem: Inglês
10.1016/j.ica.2010.05.026
ISSN1873-3255
AutoresGuang‐Xiang Liu, Yu-Yong Xu, Xiao‐Ming Ren, Sadafumi Nishihara, Rong‐Yi Huang,
Tópico(s)Magnetism in coordination complexes
ResumoAbstract The hydrothermal reactions of H2PDC, AgNO3 with Eu2O3 or Tb(NO3)3·6H2O gave rise to two novel three-dimensional 4d–4f heterometallic metal–organic coordination polymers, AgEu(PDC)2 (1) and AgTb(PDC)2 (2) (H2PDC = pyridine-3,5-dicarboxylic acid), and characterized by elemental analysis, IR, thermal analysis and single-crystal X-ray diffraction. Complexes 1 and 2 crystallize in the monoclinic system, P2/c space group; the structure determination reveal that both of them are isostructural and feature an unusual three-dimensional heterometallic network structure in which infinite lanthanide-carboxylate chains are linked by [Ag(PDC)2]3− metalloligands to form a mixed-metal coordination network. Moreover, the luminescent properties of two complexes have also been investigated at room temperature.
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