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Monitoring dehydration and condensation processes of Na2HPO4 · 12H2O using thermo-Raman spectroscopy

2003; Elsevier BV; Volume: 59; Issue: 7 Linguagem: Inglês

10.1016/s1386-1425(02)00395-5

1873-3557

Anil V. Ghule, Chetan Jagdish Bhongale, Hua Chang,

Inorganic and Organometallic Chemistry

Thermal dehydration and condensation processes of disodium hydrogen phosphate dodecahydrate (Na2HPO4 · 12H2O) were monitored by thermo-Raman spectroscopy (TRS). Various hydrated forms Na2HPO4 · 12H2O, Na2HPO4 · 8H2O, Na2HPO4 · 7H2O, Na2HPO4 · 2H2O, Na2HPO4 · H2O and Na2HPO4 were observed, followed by condensation of Na2HPO4 to sodium pyrophosphate (Na4P2O7) in a dynamic thermal process. Representative Raman spectra of all the hydrated forms Na2HPO4 · 12H2O, Na2HPO4 · 8H2O, Na2HPO4 · 7H2O, Na2HPO4 · 2H2O, Na2HPO4 · H2O and Na2HPO4 were detected in both H2O and PO43− regions are reported. The thermo-Raman intensity (TRI) thermogram also showed systematic loss of water in five steps of dehydration, with the differential TRI thermogram in agreement shows five dips corresponding to the five steps of dehydration, respectively. Thermogravimetry (TG) and differential thermogravimetry (DTG) are in harmony with the results of TRS, though, the two could not resolve the steps involved.