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Artigo Revisado por pares
BIBTEX RIS

Copper-catalyzed cyanation of arenes using benzyl nitrile as a cyanide anion surrogate

2012; Royal Society of Chemistry; Volume: 48; Issue: 79 Linguagem: Inglês

10.1039/c2cc35046g

ISSN

1364-548X

Autores

Jisong Jin, Qiaodong Wen, Ping Lü, Yanguang Wang,

Tópico(s)

Oxidative Organic Chemistry Reactions

Resumo

The copper-catalyzed cyanation of arenes using benzyl nitrile as a cyanide anion surrogate furnishes aromatic nitriles in moderate to good yields. The cascade process involves a copper-catalyzed aerobic C–H oxidation, a retro-cyanohydrination, and a copper-catalyzed aerobic oxidative C–H functionalization.

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