Experimental and computational study of a reductive elimination mechanism in a methyl–Pd( ii )–CNC carbene complex
2002; Royal Society of Chemistry; Issue: 21 Linguagem: Inglês
10.1039/b207020k
ISSN1364-548X
AutoresDavid J. Nielsen, A.M. Magill, Brian F. Yates, K.J. Cavell, Brian W. Skelton, Allan H. White,
Tópico(s)Catalytic C–H Functionalization Methods
ResumoExperimental and density functional studies on the decomposition of a novel palladium–methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.
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