Synthesis and structural analysis of an infinite linear coordination network formed by the self-assembly of tetracyanocalix[4]arene ligands and silver cations
1998; Royal Society of Chemistry; Issue: 22 Linguagem: Inglês
10.1039/a807434h
ISSN1364-548X
AutoresGilles Mislin, Ernest Graf, Mir Wais Hosseini, André De Cian, Nathalie Kyritsakas, Jean Fischer,
Tópico(s)Supramolecular Self-Assembly in Materials
ResumoUsing the O-alkylation of the lower rim of the calix[4]arene to impose the 1,3-alternate conformation and the functionalisation of the upper rim to set-up four nitrile groups pointing in a divergent fashion, an exo-ligand capable of forming linear coordination networks was obtained; upon self-assembly of the latter and silver cation, a linear coordination polymer was obtained and structurally analysed in the solid state by an X-ray study.
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