Portal de Periódicos da CAPES

Effects of Gas-Phase Basicity on the Proton Transfer between Organic Bases and Trifluoroacetic Acid in the Gas Phase: Energetics of Charge Solvation and Salt Bridges †

2000; American Chemical Society; Volume: 104; Issue: 45 Linguagem: Inglês

10.1021/jp0012505

1520-5215

Eric F. Strittmatter, Richard Wong, Evan R. Williams,

Molecular Spectroscopy and Structure

The unimolecular dissociation pathways and kinetics of a series of protonated trimer ions consisting of two organic bases and trifluoroacetic acid were investigated using blackbody infrared radiative dissociation. Five bases with gas-phase basicities (GB) ranging from 238.4 to 246.2 kcal/mol were used. Both the dissociation pathways and the threshold dissociation energies depend on the GB of the base. Trimers consisting of the two most basic molecules dissociate to form protonated base monomers with an E0 ∼1.4 eV. Trimers consisting of the two least basic molecules dissociate to form protonated base dimers with an E0 ∼1.1−1.2 eV. These results indicate that the structures of the trimers change as a function of the GB of the basic molecule. The predominant structure of the protonated trimers consisting of the two most basic molecules is consistent with a salt bridge in which both of the basic molecules are protonated, and the trifluoroacetic acid molecule is deprotonated, whereas the predominant structure of the protonated trimers consisting of the two least basic molecules are consistent with charge-solvated complexes in which the proton is shared. The structure of the trimer consisting of the base of intermediate basicity is less clear; it dissociates to form primarily protonated base dimer, but has an E0 ∼1.2 eV. These results are consistent with the structure of this trimer as a salt bridge, but the resulting dissociation A-·BH+ product does not appear to be stable as an ion pair in the dissociative transition state.