Amavadine as a catalyst for the peroxidative halogenation, hydroxylation and oxygenation of alkanes and benzene
2000; Royal Society of Chemistry; Issue: 19 Linguagem: Inglês
10.1039/b005513l
ISSN1364-548X
AutoresPatrícia M. Reis, J L Pombeiro Armando, Luanna Carla Lima Da Silva, João J. R. Fraústo da Silva, Armando J. L. Pombeiro,
Tópico(s)Heme Oxygenase-1 and Carbon Monoxide
ResumoSynthetic amavadine models, [V(HIDPA)2]2− and [V(HIDA)2]2− [where HIDPA and HIDA stand for the basic forms of 2,2′-(hydroxyimino)dipropionic and 2,2′-(hydroxyimino)diacetic acid, respectively], exhibit haloperoxidase- or peroxidase-type activities, and act as catalysts for the selective peroxidative monohalogenation, hydroxylation or oxo-functionalization of alkanes or aromatic compounds such as benzene and mesitylene at room temperature.
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