The photoelectron spectrum of an unstable species in the pyrolysis products of dimethyldisulphide
1972; Elsevier BV; Volume: 15; Issue: 4 Linguagem: Inglês
10.1016/0009-2614(72)80367-1
ISSN1873-4448
AutoresHarold W. Kroto, Roger J. Suffolk,
Tópico(s)Atmospheric Ozone and Climate
ResumoA new photoelectron spectrum has been observed in the pyrolysis products of dimethyldisulphide, CH3SSCH3. As the major product under these conditions is known to be the unstable species thioformaldehyde, H2CS, the new spectrum has been assigned to this molecule. The first ionisation potential is 9.34 ± 0.01 eV which compares well with the result obtained by other techniques. The evidence for this assignment is discussed.
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