Portal de Periódicos da CAPES

Thermal Decomposition of hydrazinium monoperchlorate in the solid state

1976; Elsevier BV; Volume: 17; Issue: 3 Linguagem: Inglês

10.1016/0040-6031(76)80075-5

1872-762X

V. R. Pai Verneker, Amit Sharma, Suresh Jain,

Chemical Thermodynamics and Molecular Structure

Hydrazinium monoperchlorate (HP-1) has been shown to decompose thermally in the solid state according to the chemical equation: The activation energy for the evolution of HCl as determined mass spectrometrically is 8.05 kcal mol−1 in the temperature range of 80 to 120°C. The rate of decomposition is seen to be altered by doping HP-1 with small concentrations of SO2−4, Ca2+ and Al3+.