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Electroreductive synthesis of acylsilanes from acylimidazoles

1995; Elsevier BV; Volume: 36; Issue: 48 Linguagem: Inglês

10.1016/0040-4039(95)01888-o

1873-3581

Naoki Kise, H. Kaneko, Norihisa Uemoto, Jun‐ichi Yoshida,

Chemical Synthesis and Reactions

Abstract Electroreduction of acylimidazoles in the presence of chlorotrimethylsilane gave the corresponding acylsilanes in satisfactory yields. Acylsilanes having a functional group such as an alkoxycarbonyl or chloro group also were synthesized effcctively.