Electrocatalytic hydrogen evolution using amorphous tungsten phosphide nanoparticles
2014; Royal Society of Chemistry; Volume: 50; Issue: 75 Linguagem: Inglês
10.1039/c4cc04709e
ISSN1364-548X
AutoresJoshua M. McEnaney, J. Chance Crompton, Juan F. Callejas, Eric J. Popczun, Carlos G. Read, Nathan S. Lewis, Raymond E. Schaak,
Tópico(s)Advanced battery technologies research
ResumoAmorphous tungsten phosphide (WP), which has been synthesized as colloidal nanoparticles with an average diameter of 3 nm, has been identified as a new electrocatalyst for the hydrogen-evolution reaction (HER) in acidic aqueous solutions. WP/Ti electrodes produced current densities of −10 mA cm−2 and −20 mA cm−2 at overpotentials of only −120 mV and −140 mV, respectively, in 0.50 M H2SO4(aq).
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