Rapid synthesis of Mn0.65Zn0.35Fe2O4/SiO2 homogeneous nanocomposites by modified sol–gel auto-combustion method
2004; Elsevier BV; Volume: 273; Issue: 1-2 Linguagem: Inglês
10.1016/j.jcrysgro.2004.08.025
ISSN1873-5002
AutoresShifeng Yan, Wei Ling, Enle Zhou,
Tópico(s)Iron oxide chemistry and applications
ResumoMnZn-ferrite/SiO2 nanocomposites with different silica content were successfully fabricated by a novel modified sol–gel auto-combustion method using citric acid as a chelating agent and tetraethyl orthosilicate (TEOS) as the source of silica matrix. The auto-combustion nature of the dried gel was studied by X-ray diffraction (XRD), Infrared spectra (IR), thermogravimetry (TG) and differential thermal analysis (DTA). Transmission electron microscope (TEM) observation shows that the MnZn-ferrite particles are homogeneously dispersed in silica matrix after auto-combustion of the dried gels. The magnetic properties vary with the silica content. The transition from the ferromagnetic to paramagnetic state is observed by Mössbauer spectra measurement with the increasing silica content. Vibrating sample magnetometer (VSM) shows that the magnetic properties of Mn0.65Zn0.35Fe2O4/SiO2 nanocomposites strongly depend on the silica content.
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