Portal de Periódicos da CAPES

Curcumin: A naturally occurring long‐wavelength photosensitizer for diaryliodonium salts

2005; Wiley; Volume: 43; Issue: 21 Linguagem: Inglês

10.1002/pola.21017

1099-0518

James V. Crivello, Umut Bulut,

Dyeing and Modifying Textile Fibers

Abstract Curcumin, a naturally occurring, intensely yellow dye extracted from the spice turmeric, is an efficient photosensitizer for diaryliodonium salt photoinitiators at wavelengths ranging from 340 to 535 nm. With curcumin as a photosensitizer, it is possible to carry out the cationic photopolymerization of a wide variety of epoxide, oxetane, and vinyl monomers with long‐wavelength UV and visible light. An example of the photopolymerization of an epoxide monomer with ambient solar irradiation is provided. Several other curcumin analogues were synthesized, and their use as photosensitizers is examined. With such photosensitizers, the range of spectral sensitivity can be extended well into the visible region of the electromagnetic spectrum. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5217–5231, 2005