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Raman Spectra and Force Constants for OsO4 and XeO4

1970; American Institute of Physics; Volume: 52; Issue: 11 Linguagem: Inglês

10.1063/1.1672838

1520-9032

John L. Huston, Howard H. Claassen,

Gas Sensing Nanomaterials and Sensors

Raman spectra are presented for OsO4 vapor, and for XeO4 vapor and solid. Observed fundamental frequencies (in cm−1) for gaseous OsO4 are 965.2(a1), 333.1(e), 960.1(f2), and 322.7(f2). For XeO4 they are 773(a1) for the vapor, and 767.1(a1), 277(e), 867(f2), and 303-f2) for the solid. The Urey–Bradley constant F is 0.32 for OsO4, and −0.18 mdyn/Å for XeO4.