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A New CuI Complex that Mimics the Cresolase Reaction of Tyrosinase and the Crystal Structure of its Oxygenated CuII Complex

2002; Wiley; Volume: 2002; Issue: 4 Linguagem: Inglês

10.1002/1099-0682(200203)2002

1099-0682

Vieri Fusi, Antoni Llobet, J. Mahı́a, Mauro Micheloni, Paola Paoli, Xavi Ribas, Patrizia Rossi,

Metal-Catalyzed Oxygenation Mechanisms

A new dinuclear CuII complex with a unique structural arrangement and containing a doubly bridged macrocyclic ligand has been prepared from two different routes, one of which involves the reaction of oxygen and a CuI precursor, thus mimicking the cresolase activity of tyrosinase