Artigo Revisado por pares

Lead chloride solubility and density data in binary aqueous solutions

1987; Elsevier BV; Volume: 17; Issue: 3 Linguagem: Inglês

10.1016/0304-386x(87)90063-6

ISSN

1879-1158

Autores

K Tan, Katharina Bartels, Pierre Bédard,

Tópico(s)

Chemical and Physical Properties in Aqueous Solutions

Resumo

Research and development work on a ferric chloride leach process for lead-silver containing concentrates required mapping of the PbCl2 solubility as a function of temperature and various co-electrolyte concentrations. A pycnometric sampling method was used to determine the solubility of PbCl2 and the density of the corresponding PbCl2-saturated solutions in aqueous HCl and NaCl at temperatures between 20 to 100°C. The results were fitted to a selection of parametric equations, which are presented in compact tabular and graphical forms. In addition, three-dimensional PbCl2 solubility surfaces of pseudo-binary systems as a function of temperature were generated, and some fundamental relationships were extracted from the data.

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