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Artigo Revisado por pares
BIBTEX RIS

An Electron‐Rich [4]Radialene

1989; Wiley; Volume: 28; Issue: 12 Linguagem: Inglês

10.1002/anie.198916631

ISSN

1521-3773

Autores

Antonio Fronda, Gerhard Maas,

Tópico(s)

Synthesis and Reactivity of Heterocycles

Resumo

A new type of bis(diazo) compound, a stable, electron-rich [4] radialene, and an unusual pentacyclic polyketal are the fruits of this investigation. Catalytic decomposition of silane 1 produces the tricyclic compound 2, whose four-membered ring is folded at an angle of 35.0°. Acid hydrolysis of 2 gives the tetra(oxahomo)cubane 3.

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