Reactivity of Electrophilic Terminal Phosphinidene Complexes: P−P Bond Forming Reactions with Phosphines and Diphosphines
2001; American Chemical Society; Volume: 20; Issue: 22 Linguagem: Inglês
10.1021/om010640q
ISSN1520-6041
AutoresB.T. Sterenberg, K.A. Udachin, Arthur J. Carty,
Tópico(s)Organophosphorus compounds synthesis
ResumoReaction of the electrophilic phosphinidene complex [Cp*Mo(CO)3{PNiPr2}][AlCl4] with triethylphosphine results in reversible coordination of the phosphine to the phosphinidene phosphorus atom followed by carbonyl displacement at the metal. Phosphine-coordinated phosphinidene complexes with P−P bonds can be isolated by using diphosphines which coordinate first to the phosphinidene and then chelate to the phosphinidene and metal atoms.
Referência(s)