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Spectroscopic Observation of Matrix‐Isolated Carbonic Acid Trapped from the Gas Phase

2010; Wiley; Volume: 50; Issue: 8 Linguagem: Inglês

10.1002/anie.201004729

1521-3773

Jürgen Bernard, Markus Seidl, Ingrid Kohl, Klaus R. Liedl, Erwin Mayer, Óscar Gálvez, Hinrich Grothe, Thomas Loerting,

Advanced Chemical Physics Studies

Against all odds: Carbonic acid molecules were trapped from the gas phase in a solid noble-gas matrix at <10 K and studied by IR spectroscopy. The 2H and and 13C isotopologues were also examined. Gas-phase carbonic acid is thought to exist as a 1:10:1 mixture of two monomeric conformers and the cyclic dimer (H2CO3)2. This data is vital in the search for gas-phase carbonic acid in astrophysical environments. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.