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New Chiral Porphyrins—Syntheses and Molecular Recognition of Amino Acid Esters

1993; Wiley; Volume: 32; Issue: 5 Linguagem: Inglês

10.1002/anie.199307231

1521-3773

Yasuhisa Kuroda, Yusuke Kato, Takuji Higashioji, Hisanobu Ogoshi,

Porphyrin and Phthalocyanine Chemistry

A three-point interaction important for chiral recognition is possible with the Zn complexes of the new porphyrins of type 1. Coordination to the metal atom, hydrogen bonding, and steric repulsion contribute to ligand–receptor binding between amino acid esters and Zn porphyrins.