PbCl 2 /Ga bimetal redox system-mediated carbon–carbon bond formation reactions between carbonyl compounds and ethyl trichloroacetate and iodoacetonitrile

1995; Issue: 3 Linguagem: Inglês

10.1039/p19950000189

ISSN

2050-8255

Autores

Xiaolin Zhang, Ying Han, Wen-Tian Tao, Yao‐Zeng Huang,

Tópico(s)

Catalytic C–H Functionalization Methods

Resumo

In the presence of lead dichloride and a metallic gallium bimetal redox system, carbonyl compounds reacted with ethyl trichloroacetate and iodoacetonitrile to afford ethyl β-substituted α,α-dichloropropionates and β-hydroxy nitriles, respectively, in moderate to excellent yields.

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