Novel 2-aza-allylidene complexes: synthesis and X-ray structure of trans-Br(CO)4W[CNCPh2]
1985; Royal Society of Chemistry; Issue: 9 Linguagem: Inglês
10.1039/c39850000537
ISSN2050-5639
AutoresHelmut Fischer, Friedrich Seitz, J. RIEDE,
Tópico(s)Chemical Synthesis and Analysis
ResumoThe replacement of the trans-CO group by Br– in cationic [(CO)5WCNCR2]AlBr4 complexes causes a drastic change in the geometry of the CNCR2 ligand; the molecular structure of the phenyl-substituted product, trans-Br(CO)4W[CNCPh2], is established by single crystal X-ray diffraction.
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