Dramatic Influence of the Electronic Structure on the Conductivity through Open‐ and Closed‐Shell Molecules
2009; Volume: 21; Issue: 10-11 Linguagem: Inglês
10.1002/adma.200801707
ISSN1521-4095
AutoresNúria Crivillers, Carmen Munuera, Marta Mas‐Torrent, Cláudia Simão, Stefan T. Bromley, Carmen Ocal, Concepció Rovira, Jaume Veciana,
Tópico(s)Nanofabrication and Lithography Techniques
ResumoAdvanced MaterialsVolume 21, Issue 10-11 p. 1177-1181 Communication Dramatic Influence of the Electronic Structure on the Conductivity through Open- and Closed-Shell Molecules Núria Crivillers, Núria Crivillers Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Search for more papers by this authorCarmen Munuera, Carmen Munuera Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain)Search for more papers by this authorMarta Mas-Torrent, Marta Mas-Torrent Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Search for more papers by this authorClaudia Simão, Claudia Simão Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Search for more papers by this authorStefan T. Bromley, Stefan T. Bromley Departament de Química Física and Institut de Recerca de Química Teòrica i Computacional (IQTCUB) Universitat de Barcelona, E-08028 Barcelona (Spain) Institució Catalana de Recerca i Estudis Avançats (ICREA) E-08010 Barcelona (Spain)Search for more papers by this authorCarmen Ocal, Corresponding Author Carmen Ocal [email protected] Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain)Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain).Search for more papers by this authorConcepció Rovira, Concepció Rovira Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Search for more papers by this authorJaume Veciana, Corresponding Author Jaume Veciana [email protected] Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain).Search for more papers by this author Núria Crivillers, Núria Crivillers Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Search for more papers by this authorCarmen Munuera, Carmen Munuera Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain)Search for more papers by this authorMarta Mas-Torrent, Marta Mas-Torrent Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Search for more papers by this authorClaudia Simão, Claudia Simão Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Search for more papers by this authorStefan T. Bromley, Stefan T. Bromley Departament de Química Física and Institut de Recerca de Química Teòrica i Computacional (IQTCUB) Universitat de Barcelona, E-08028 Barcelona (Spain) Institució Catalana de Recerca i Estudis Avançats (ICREA) E-08010 Barcelona (Spain)Search for more papers by this authorCarmen Ocal, Corresponding Author Carmen Ocal [email protected] Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain)Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain).Search for more papers by this authorConcepció Rovira, Concepció Rovira Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Search for more papers by this authorJaume Veciana, Corresponding Author Jaume Veciana [email protected] Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain) Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Bellaterra (Spain)Institut de Ciencia de Materials de Barcelona (ICMAB-CSIC) Campus de la UAB 08193-Bellaterra (Spain).Search for more papers by this author First published: 12 March 2009 https://doi.org/10.1002/adma.200801707Citations: 42AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract The conductivity through two self-assembled monolayers (SAMs) on gold based on the closed-and open-shell form of a polychlorotriphenylmethyl (PTM) derivative were investigated using 3D-mode conductive scanning force microscopy, and striking differences were observed, caused by their highly distinct electronic structure. Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description adma_200801707_sm_suppdata.pdf307.8 KB suppdata Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1a H. B. Akkerman, P. W. M. Blom, D. M. de Leeuw, B. de Boer, Nature 2006, 44, 69. 1b V. Ferri, M. Elbing, G. Pace, M. D. Dickey, M. Zharnikow, P. Samorì, M. Mayor, M. A. Rampi, Angew. Chem. Int. Ed. 2008, 47, 3407. 1c A. J. Kronemijer, H. B. Akkerman, T. Kudernac, B. J. van Wees, B. L. Feringa, P. W. M. Blom, B. De Boer, Adv. Mater. 2008, 20, 1467. 2a A. Nitzan, M. A. Ratner, Science 2003, 300, 1384. 2b F. Chen, J. Hihath, Z. F. Huang, X. L. Li, N. J. Tao, Annu. Rev. Phys. Chem. 2007, 58, 535. 2c H. Haick, D. Cahen, Prog. Surf. Sci. 2008, 83, 217. 3a B. Kim, J. M. Beebe, Y. Jun, X.-Y. Zhu, C. D. Frisbie, J. Am. Chem. Soc. 2006, 128, 4970. 3b K. Kitagawa, T. Morita, S. Kimura, Langmuir 2005, 21, 10624. 3c R.-F.-.F. Fan, J. Yang, L. Cai, D. W. Price, S. M. Dirk, Jr., D. V. Kosynkin, Y. Yao, A. M. Rawlett, J. M. Tour, A. J. Bard, J. Am. Chem. Soc. 2002, 124, 5550. 3d K. Seo, A. V. Koncheko, J. Lee, G. S. Band, H. Lee, J. Am. Chem. Soc. 2008, 130, 2553. 4a A. Salomon, D. Cahen, S. Lindsay, J. Tomfohr, V. B. Engelkes, C. D. Frisbie, Adv. Mater. 2003, 15, 1881. 4b V. B. Engelkes, J. M. Beebe, C. Daniel Frisbie, J. Phys. Chem. B 2005, 109, 16801. 5a X.-S. Zhou, Z.-B. Chen, S.-H. Liu, S. Jin, L. Liu, H.-M. Zhang, Z.-X. Xie, Y.-B. Jiang, B.-W. Mao, J. Phys. Chem. C 2008, 112, 3935. 5b D. J. Wold, R. Haag, M. A. Rampi, C. D. Frisbie, J. Phys. Chem. B 2002, 106, 2813. 6a K. Seo, A. V. Konchenko, J. Lee, G. S. Bang, H. Lee, J. Am. Chem. Soc. 2008, 130, 2553. 6b B. Kim, J. M. Beebe, C. Oliver, S. Rigaut, D. Touchard, J. G. Kushmerick, X.-Y. Zhu, C. D. Frisbie, J. Phys. Chem. C 2007, 111, 7521. 6c W. Haiss, H. Zalinge, S. J. Higgins, D. Bethell, H. Höbenreich, D. J. Schiffrin, R. J. Nichols, J. Am. Chem. Soc. 2003, 125, 15294. 6d X. Li, J. Hihath, F. Chen, T. Masuda, L. Zang, N. Tao, J. Am. Chem. Soc. 2007, 129, 11535. 7 J. M. Mativetsky, G. Pace, M. Elbing, M. A. Rampi, M. Mayor, P. Samorì, J. Am. Chem. Soc. 2008, 130, 9192. 8a M. Ballester, J. Riera, J. Castaner, C. Badía, J. M. Monsó, J. Am. Chem. Soc. 1971, 93, 2215. 8b C. Sporer, I. Ratera, D. Ruiz-Molina, J. Vidal-Gancedo, K. Wurst, P. Jaitner, C. Rovira, J. Veciana, J. Phys. Chem. Solids 2004, 65, 753. 9a N. Crivillers, M. Mas-Torrent, S. Perruchas, N. Roques, J. Vidal-Gancedo, J. Veciana, C. Rovira, L. Basabe-Desmonts, B. J. Ravoo, M. Crego-Calama, D. N. Reinhoudt, Angew. Chem. Int. Ed. 2007, 46, 2215. 9b N. Crivillers, M. Mas-Torrent, J. Vidal-Gancedo, J. Veciana, C. Rovira, J. Am. Chem. Soc. 2008, 130, 5499. 9c O. Shekhah, N. Roques, V. Mugnaini, C. Munuera, C. Ocal, J. Veciana, C. Wöll, Langmuir 2008, 24, 6640. 10 Y. T. Kim, R. L. McCarley, A. J. Bard, J. Phys. Chem. 1992, 96, 7416. 11a J. Lakkari, K. Kleemola, M. Meretoja, T. Ollonqvist, J. Kankare, Langmuir 1998, 14, 1705. 11b J. J. W. M. Rosink, M. A. Blauw, L. J. Geerligs, E. van der Drigt, B. A. C. Rousseuw, S. Radelaar, W. G. Sloof, E. J. M. Fakkeldij, Langmuir 2000, 16, 4547. 12 M. Ballester, J. Riera, J. Castañer, C. Rovira, J. Veciana, C. Onrubia, J. Org. Chem. 1983, 48, 3716. 13a B. I. Rosario, E. R. Fachini, J. Hernandez, M. E. Pérez-Davis, C. R. Cabrera, Langmuir 2006, 22, 6102. 13b J. M. Brockman, A. G. Frutos, R. M. Corn, J. Am. Chem. Soc. 1999, 121, 8044. 14 C. E. D. Chidsey, Science 1991, 251, 919. 15 C. Munuera, E. Barrena, C. Ocal, Nanotechnology 2007, 18, 125505. 16a R. L. McCreery, Chem. Mater. 2004, 16, 4477. 16b R. E. Holmlin, R. Haag, M. L. Chabinyc, R. F. Ismagilov, A. E. Cohen, A. Terfort, M. A. Rampi, G. M. Whitesides, J. Am. Chem. Soc. 2001, 123, 5075. 17a S. J. Luo, K. L. Yao, Phys. Rev. B 2003, 67, 214429. 17b M. Mas-Torrent, N. Crivillers, V. Mugnaini, I. Ratera, C. Rovira, J. Veciana, J. Mater. Chem. 2009, DOI: 10.1039/b809875a. 18 I. Horcas, R. Fernandez, J. M. Gomez-Rodriguez, J. Colchero, J. Gomez-Herrero, A. M. Baro, Rev. Sci. Instrum. 2007, 78, 013705. 19 P. J. Stephens, F. J. Devlin, C. F. Chabalowski, M. J. Frisch, J. Phys. Chem. 1994, 98, 11623. 20 M. F. Guest, I. J. Bush, H. J. J. van Dam, P. Sherwood, J. M. H. Thomas, J. H. van Lenthe, R. W. A. Havenith, J. Kendrick, Mol. Phys. 2005, 103, 719. Citing Literature Volume21, Issue10-11March 20, 2009Pages 1177-1181 ReferencesRelatedInformation
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