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A convenient synthesis of β-alkynylpropionic acids from β-propiolactones. Synthesis of 4,4,5,5-tetradehydro-9(O)-methano-Δ6(9α)-PGI1

1986; Elsevier BV; Volume: 27; Issue: 1 Linguagem: Inglês

10.1016/s0040-4039(00)83948-9

1873-3581

Masaki Shinoda, Katsuhiko Iseki, T. OGURI, Yosio Hayasi, Shun‐ichi Yamada, Masakatsu Shibasaki,

Carbohydrate Chemistry and Synthesis

A new prostacyclin analog, 4,4,5,5-tetradehydro-9(0)-methano-gD6(9α)-PGI, has been synthesized by utilizing the regiocontrolled cleavage of the β-propiolactone uith the dialkylaluminum acetylide.