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Artigo Revisado por pares
BIBTEX RIS

The stereospecific synthesis of a carbacyclin analogue using the protodesilylation of an allylsilane

1989; Elsevier BV; Volume: 30; Issue: 42 Linguagem: Inglês

10.1016/s0040-4039(00)76195-8

ISSN

1873-3581

Autores

Ian Fleming, Dick Higgins,

Tópico(s)

Synthetic Organic Chemistry Methods

Resumo

Protodesilylation of the allylsilane 15 gives the E-carbacyclin 16, with excellent (>96:4) control of the geometry of the double bond exocyclic to the ring.

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Tetrahedron Letters
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