Portal de Periódicos da CAPES

Transition-metal complex catalyzed polyfluoroalkylation. I. Facile addition of polyfluoroalkyl halides to carbon-carbon multiple bonds

1984; Elsevier BV; Volume: 25; Issue: 3 Linguagem: Inglês

10.1016/s0040-4039(00)99868-x

1873-3581

Takamasa Fuchikami, Iwao Ojima,

Fluorine in Organic Chemistry

Addition of polyfluoroalkyl halides to alkynes and alkenes bearing a variety of substituents is effected by the catalysis of iron, cobalt and ruthenium carbonyl complexes to give the corresponding adducts in good to excellent yields under mild conditions.