Neutral H 2 O 2 Synthesis by Electrolysis of Water and O 2
2008; Wiley; Volume: 47; Issue: 10 Linguagem: Inglês
10.1002/anie.200704431
ISSN1521-3773
AutoresIchiro Yamanaka, Toru Murayama,
Tópico(s)Advanced Photocatalysis Techniques
ResumoAngewandte Chemie International EditionVolume 47, Issue 10 p. 1900-1902 Communication Neutral H2O2 Synthesis by Electrolysis of Water and O2 Ichiro Yamanaka, Ichiro Yamanaka [email protected] Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8552, Japan, Fax: (+81) 3-5734-2144Search for more papers by this authorToru Murayama, Toru Murayama Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8552, Japan, Fax: (+81) 3-5734-2144Search for more papers by this author Ichiro Yamanaka, Ichiro Yamanaka [email protected] Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8552, Japan, Fax: (+81) 3-5734-2144Search for more papers by this authorToru Murayama, Toru Murayama Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8552, Japan, Fax: (+81) 3-5734-2144Search for more papers by this author First published: 15 February 2008 https://doi.org/10.1002/anie.200704431Citations: 148Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Direct, safe, and continuous synthesis of neutral H2O2 solutions with concentrations of up to 8 wt % from O2 and water has been accomplished by an improved electrolysis method involving a solid-polymer electrolyte (SPE). The formation and accumulation of neutral H2O2 were strongly enhanced by exposing the cathode to a stream of O2. References 1M. C. Campos-Martin, G. Blanco-Brieva, J. L. G. Fierro, Angew. Chem. 2006, 118, 7116–7139; Angew. Chem. Int. Ed. 2006, 45, 6962–6984. 2H. Reidl, G. Pfleirender, US 2215883, 1940. 3P. C. Foller, R. T. Bombard, J. Appl. Electrochem. 1995, 25, 613–627. 4Y. Izumi, US 4009252, 1978. 5L. W. Gosset, US 4681751, 1988. 6G. Blanco-Brieva, E. Cano-Serrano, M. C. Campos-Martin, J. L. G. Fierro, Chem. Commun. 2004, 1184–1185. 7P. Landon, P. J. Collier, A. J. Papworth, C. J. Kiely, G. J. Hutchings, Chem. Commun. 2002, 2058–2059. 8T. Ishihara, Y. Ohura, S. Yoshida, Y. Hata, H. Nishiguchi, Y. Takita, Appl. Catal. A 2005, 291, 215–221. 9K. Otsuka, I. Yamanaka, Electrochim. Acta 1990, 35, 319–322. 10I. Yamanaka, T. Hashimoto, K. Otsuka, Chem. Lett. 2002, 852–853. 11V. R. Choudhary, A. G. Gaiward, S. D. Sansare, Angew. Chem. 2001, 113, 1826–1829; Angew. Chem. Int. Ed. 2001, 40, 1776–1779. 12S. Melada, F. Pinna, G. Strukul, S. Perathoner, G. Centi, J. Catal. 2006, 237, 213–219. 13I. Yamanaka, T. Onizawa, S. Takenaka, K. Otsuka, Angew. Chem. 2003, 115, 3781–3783; Angew. Chem. Int. Ed. 2003, 42, 3653–3655. 14I. Yamanaka, T. Onizawa, H. Suzuki, N. Hanaizumi, Chem. Lett. 2006, 35, 1330–1331. 15Z. Ogumi, K. Nishio, S. Yoshizawa, Electrochim. Acta 1981, 26, 1779–1782. 16K. Otsuka, I. Yamanaka, Catal. Today 1998, 41, 311–325. Citing Literature Volume47, Issue10February 22, 2008Pages 1900-1902 ReferencesRelatedInformation
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