ARYLPYRIDINES: PART II. REACTION OF PHENYLLITHIUM WITH 3-METHOXY- AND 3-AMINO-PYRIDINE
1960; NRC Research Press; Volume: 38; Issue: 9 Linguagem: Inglês
10.1139/v60-203
ISSN1480-3291
AutoresR. A. Abramovitch, Albert D. Notation,
Tópico(s)Synthesis and Reactions of Organic Compounds
ResumoPhenyllithium has been shown to react with 3-methoxy- and 3-amino-pyridine to give exclusively 3-methoxy-2-phenylpyridine and 3-amino-2-phenylpyridine respectively. The orientation of the products has been established unambiguously. None of the 2,5-isomer was detected in either case. An explanation for this unique orientation is suggested.
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