Photoenolisation of conjugated esters: Synthesis of a San Jose scale pheromone by partially regio-controlled photochemical deconjugation.
1986; Elsevier BV; Volume: 27; Issue: 46 Linguagem: Inglês
10.1016/s0040-4039(00)85264-8
ISSN1873-3581
AutoresDomenic A. Lombardo, Alan C. Weedon,
Tópico(s)Marine Sponges and Natural Products
ResumoThe photochemical deconjugation reaction of an α,β-unsaturated ester is applied to the synthesis of one of the components of the San Jose scale pheromone, compound 1. The use of a weak organic base as a means of control of the regiochemistry of the deconjugation reaction was demonstrated.
Referência(s)