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BIBTEX RIS

Ruthenium Nanoparticles Stabilized by N‐Heterocyclic Carbenes: Ligand Location and Influence on Reactivity

2011; Wiley; Volume: 50; Issue: 50 Linguagem: Inglês

10.1002/anie.201106348

ISSN

1521-3773

Autores

Patricia Lara, Orestes Rivada‐Wheelaghan, Salvador Conejero, Romuald Poteau, Karine Philippot, Bruno Chaudret,

Tópico(s)

Asymmetric Hydrogenation and Catalysis

Resumo

NHCs go nano: Ruthenium nanoparticles were formed from (cyclooctadiene)(cyclooctatriene)ruthenium(0) and stabilized by N-heterocyclic carbenes (NHCs). Solid-state NMR spectroscopy revealed both the coordination of the NHC ligands on the surface of the particles and their surface reactivity.

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