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Quaternary Ammonium Periodate as a New Oxidizing Agent

1980; Oxford University Press; Volume: 53; Issue: 2 Linguagem: Inglês

10.1246/bcsj.53.565

1348-0634

Katsuhiko Inomata, Yukiharu Nakayama, Hiroshi Kotake,

Oxidative Organic Chemistry Reactions

Abstract Quaternary ammonium periodate has been found to be a useful oxidizing agent to convert a 1,2-diol and an olefin to the corresponding carbonyl compound in anhydrous aprotic solvents. The resulting carbonyl compounds have been reacted with alkyllithium to prepare alcohols in one-pot from a 1,2-diol or an olefin.