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The Modular Synthesis of Functional Porous Coordination Networks

2007; American Chemical Society; Volume: 129; Issue: 50 Linguagem: Inglês

10.1021/ja0752540

1943-2984

Masaki Kawano, T. Kawamichi, T. Haneda, Takahiro Kojima, Makoto Fujita,

Supramolecular Chemistry and Complexes

Facile control of pore nature by simply replacing a cartridge is a new approach to the library synthesis of a family of porous networks. We succeeded in the preparation of various biporous networks via modular synthesis and the fine-tuning of the channel atmosphere by simple modification of the cartridge molecules. Noteworthy is that alcohol molecules are selectively recognized by the biporous network.