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Low-valent organotitanium species and their applications to organic synthesis

1991; Elsevier BV; Volume: 405; Issue: 1 Linguagem: Inglês

10.1016/0022-328x(91)83153-u

1872-8561

Yi Dang, H. J. Geise,

Coordination Chemistry and Organometallics

Low-valent organotitanium complexes and their synthetic applications are reviewed with emphasis on carboncarbon bond formation. The survey covers (1) reductive coupling, (2) elimination, (3) carbonyl methylenation and general alkylidenation, (4) reduction and (5) fixation and/or reduction of small molecules.