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Effect of alkylaluminum cocatalyst on ethylene polymerization with nickel-α-diimine complex

2007; Elsevier BV; Volume: 325; Issue: 1 Linguagem: Inglês

10.1016/j.apcata.2007.03.007

1873-3875

Caroline Guterres de Souza, Roberto Fernando de Souza, Kátia Bernardo-Gusmão,

Synthetic Organic Chemistry Methods

Ethylene polymerization was carried out with two nickel(II)(α-diimine) complexes: 1,4-bis(2,6-diisopropylphenyl)-acenaphthenediimine-dichloro-nickel(II) (1) and 1,4-bis(2,6-diisopropylphenyl)-ethanediimine-dichloronickel(II) (2) combined with alkylaluminum activators like methylalumoxane (MAO), trimethylaluminum (TMA), and ethylaluminum sesquichloride (EASC). The activity of these systems and the proprieties of the polymeric materials are strongly influenced by the choice of the ligand structure and, more dramatically, by the nature of the cocatalyst. EASC has been shown as giving higher productivities than TMA or MAO with both complexes, attaining 3966 kg PE/(mol Ni·h). Complex 2 gives lower productivities but produced polymers with higher polymer melting points (Tm) and crystallinity than catalyst 1.