A Topology Paradigm for Metal‐Organic Zeolites
2003; Wiley; Volume: 42; Issue: 22 Linguagem: Inglês
10.1002/anie.200250534
ISSN1521-3773
AutoresЭдуард Б. Русанов, Vira V. Ponomarova, V.V. Komarchuk, H. Stoeckli‐Evans, Elena Fernandez‐Ibañez, Fritz Stoeckli, Joachim Sieler, Konstantin V. Domasevitch,
Tópico(s)Covalent Organic Framework Applications
ResumoAngewandte Chemie International EditionVolume 42, Issue 22 p. 2499-2501 Communication A Topology Paradigm for Metal-Organic Zeolites† Eduard B. Rusanov Dr., Eduard B. Rusanov Dr. Institute of Organic Chemistry, Murmanskaya Str. 5, Kiev-94, 02094, UkraineSearch for more papers by this authorVira V. Ponomarova Dr., Vira V. Ponomarova Dr. Inorganic Chemistry Department, Kiev University, Volodimirska Street 64, Kiev 01033, Ukraine, Fax: (+380) 44-296-2467Search for more papers by this authorVasiliy V. Komarchuk, Vasiliy V. Komarchuk Inorganic Chemistry Department, Kiev University, Volodimirska Street 64, Kiev 01033, Ukraine, Fax: (+380) 44-296-2467Search for more papers by this authorHelen Stoeckli-Evans Prof. Dr., Helen Stoeckli-Evans Prof. Dr. Chemistry Department, University of Neuchâtel, Av. de Bellevaux 51, Neuchâtel, 2007, SwitzerlandSearch for more papers by this authorElena Fernandez-Ibañez, Elena Fernandez-Ibañez Chemistry Department, University of Neuchâtel, Av. de Bellevaux 51, Neuchâtel, 2007, SwitzerlandSearch for more papers by this authorFritz Stoeckli Prof. Dr., Fritz Stoeckli Prof. Dr. Chemistry Department, University of Neuchâtel, Av. de Bellevaux 51, Neuchâtel, 2007, SwitzerlandSearch for more papers by this authorJoachim Sieler Prof. Dr., Joachim Sieler Prof. Dr. Institut für Anorganische Chemie, Universität Leipzig, Linnéstrasse 3, 04103 Leipzig, GermanySearch for more papers by this authorKonstantin V. Domasevitch Dr., Konstantin V. Domasevitch Dr. [email protected] Inorganic Chemistry Department, Kiev University, Volodimirska Street 64, Kiev 01033, Ukraine, Fax: (+380) 44-296-2467Search for more papers by this author Eduard B. Rusanov Dr., Eduard B. Rusanov Dr. Institute of Organic Chemistry, Murmanskaya Str. 5, Kiev-94, 02094, UkraineSearch for more papers by this authorVira V. Ponomarova Dr., Vira V. Ponomarova Dr. Inorganic Chemistry Department, Kiev University, Volodimirska Street 64, Kiev 01033, Ukraine, Fax: (+380) 44-296-2467Search for more papers by this authorVasiliy V. Komarchuk, Vasiliy V. Komarchuk Inorganic Chemistry Department, Kiev University, Volodimirska Street 64, Kiev 01033, Ukraine, Fax: (+380) 44-296-2467Search for more papers by this authorHelen Stoeckli-Evans Prof. Dr., Helen Stoeckli-Evans Prof. Dr. Chemistry Department, University of Neuchâtel, Av. de Bellevaux 51, Neuchâtel, 2007, SwitzerlandSearch for more papers by this authorElena Fernandez-Ibañez, Elena Fernandez-Ibañez Chemistry Department, University of Neuchâtel, Av. de Bellevaux 51, Neuchâtel, 2007, SwitzerlandSearch for more papers by this authorFritz Stoeckli Prof. Dr., Fritz Stoeckli Prof. Dr. Chemistry Department, University of Neuchâtel, Av. de Bellevaux 51, Neuchâtel, 2007, SwitzerlandSearch for more papers by this authorJoachim Sieler Prof. Dr., Joachim Sieler Prof. Dr. Institut für Anorganische Chemie, Universität Leipzig, Linnéstrasse 3, 04103 Leipzig, GermanySearch for more papers by this authorKonstantin V. Domasevitch Dr., Konstantin V. Domasevitch Dr. [email protected] Inorganic Chemistry Department, Kiev University, Volodimirska Street 64, Kiev 01033, Ukraine, Fax: (+380) 44-296-2467Search for more papers by this author First published: 05 June 2003 https://doi.org/10.1002/anie.200250534Citations: 100 † The authors gratefully acknowledge support from Deutsche Forschungsgemeinschaft and an INTAS Fellowship grant (KVD) YSF 2002-310. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Unprecedented coordination polymers of hexagonal tungsten bronze topology represent a new type of metal–organic zeolites: the compounds have a microporous structure, they are thermally stable and are capable of the reversible adsorption of dichloromethane (see picture). Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2003/z50534_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1K. Seki, Chem. Commun. 2001, 1496–1497; M. Kondo, T. Yoshitomi, K. Seki, H. Matsuzaka, S. Kitagawa, Angew. Chem. Int. Ed. Engl. 1997, 36, 1725–1727; H. Li, M. Eddaoudi, M. O'Keeffe, O. M. Yaghi, Nature 1999, 402, 276–279; M. Eddaoudi, H. Li, O. M. Yaghi, J. Am. Chem. Soc. 2000, 122, 1391–1397; L. C. Tabares, J. A. R. Navarro, J. M. Salas, J. Am. Chem. Soc. 2001, 123, 383–387; Y.-H. Liu, Y.-L. Lu, H.-C. Wu, J.-C. Wang, K.-L. Lu, Inorg. Chem. 2002, 41, 2592–2597, and references therein. 2S. Noro, S. Kitagawa, M. Kondo, K. Seki, Angew. Chem. 2000, 112, 2161–2164; Angew. Chem. Int. Ed. 2000, 39, 2082–2084. 3B. F. Hoskins, R. Robson, J. Am. Chem. Soc. 1990, 112, 1546–1554. 4M. Fujita, Y. J. Kwon, S. Washizu, K. Ogura, J. Am. Chem. Soc. 1994, 116, 1151–1152; S. Noro, S. Kitagawa, M. Yamashita, T. Wada, Chem. Commun. 2002, 222–223. 5R. Robson, J. Chem. Soc. Dalton Trans. 2000, 3735–3744; B. Moulton, M. J. Zaworotko, Chem. Rev. 2001, 101, 1629–1658. 6 6aA. F. Wells, Three-Dimensional Nets and Polyhedra, Wiley-Interscience, New York, 1977; 6bA. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon, Oxford, 1986. 7M. J. Zaworotko, Chem. Commun. 2001, 1–9; S. Subramanian, M. J. Zaworotko, Angew. Chem. 1995, 107, 2295–2297; Angew. Chem. Int. Ed. Engl. 1995, 34, 2127–2129. 8I. Boldog, E. B. Rusanov, A. N. Chernega, J. Sieler, K. V. Domasevitch, Angew. Chem. 2001, 113, 3543–3546; Angew. Chem. Int. Ed. 2001, 40, 3435–3438; I. Boldog, E. B. Rusanov, A. N. Chernega, J. Sieler, K. V. Domasevitch, J. Chem. Soc. Dalton Trans. 2001, 893–897; V. V. Ponomarova, V. V. Komarchuk, I. Boldog, A. N. Chernega, J. Sieler, K. V. Domasevitch, Chem. Commun. 2002, 436–437; I. Boldog, E. B. Rusanov, J. Sieler, S. Blaurock, K. V. Domasevitch, Chem. Commun. 2003, 740–741. 92D Kagomé networks themselves were recently discovered by:B. Moulton, J. Lu, R. Hajndl, S. Hariharan, M. J. Zaworotko, Angew. Chem. 2002, 114, 2945–2948; Angew. Chem. Int. Ed. 2002, 41, 2821–2824; M. Eddaoudi, J. Kim, D. Vodak, A. Sudik, J. Wachter, M. O'Keeffe, O. M. Yaghi, Proc. Natl. Acad. Sci. USA 2002, 99, 4900–4904. 10The TGA curve for hydrated 1 a shows 4.4 % weight loss (ca. −1.4 H2O) to 425 K, then release of SO2 at 590 K, which is followed by further decomposition at 650 K. For comparison, the most stable inorganic dithionate, K2S2O6, looses SO2 at 530 K. 11PLATON/PLUTON version Jan. 1999 A. L. Spek, Acta Crystallogr. Sect. A 1990, 46, C 34. 12R. C. Bansal, J. B. Donnet, F. Stoeckli, Active Carbon, Marcel Dekker, New York, 1988, pp. 119–162; F. Stoeckli in Porosity in Carbons (Ed.: ), Arnold, London, 1995, pp. 67–92. 13F. Stoeckli, Russ. Chem. Bull. Int. Ed. 2001, 50, 2265–2272; M. M. Dubinin in Progress in Surface and Membrane Science, Vol. 19 (Ed.: ), Academic Press, London, 1975, pp. 1–69. 14B. Garrot, G. Couderc, M. H. Simonot-Grange, F. Stoeckli, Microporous Mesoporous Mater. 2002, 52, 199–206. 15W. L. Mosby, J. Chem. Soc. 1957, 3997–4003. 16G. M. Sheldrick, Acta Crystallogr. Sect. A 1990, 46, 467–473; G. M. Sheldrick, SHELXL-93, Program for Crystal Structure Refinement from Diffraction Data, University of Göttingen, Göttingen (Germany), 1993. Citing Literature Volume42, Issue22June 6, 2003Pages 2499-2501 ReferencesRelatedInformation
Referência(s)