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Ruthenium–Benzylidenes and Ruthenium–Indenylidenes as Efficient Catalysts for the Hydrogenation of Aliphatic Nitriles into Primary Amines

2012; Wiley; Volume: 4; Issue: 12 Linguagem: Inglês

10.1002/cctc.201200511

ISSN

1867-3899

Autores

Xiaowei Miao, Johan Bidange, Pierre H. Dixneuf, Cédric Fischmeister, Christian Bruneau, Jean‐Luc Dubois, Jean‐Luc Couturier,

Tópico(s)

Chemical Synthesis and Analysis

Resumo

ChemCatChemVolume 4, Issue 12 p. 1911-1916 Communication Ruthenium–Benzylidenes and Ruthenium–Indenylidenes as Efficient Catalysts for the Hydrogenation of Aliphatic Nitriles into Primary Amines Dr. Xiaowei Miao, Dr. Xiaowei Miao UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorJohan Bidange, Johan Bidange UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorProf. Pierre H. Dixneuf, Prof. Pierre H. Dixneuf UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorDr. Cédric Fischmeister, Dr. Cédric Fischmeister UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorDr. Christian Bruneau, Corresponding Author Dr. Christian Bruneau [email protected] UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorDr. Jean-Luc Dubois, Dr. Jean-Luc Dubois ARKEMA, 420 Rue d'Estienne d'Orves, 92705 Colombes (France)Search for more papers by this authorDr. Jean-Luc Couturier, Dr. Jean-Luc Couturier ARKEMA, CRRA, BP, 63 Rue Henri Moissan, 69493, Pierre-Bénite (France)Search for more papers by this author Dr. Xiaowei Miao, Dr. Xiaowei Miao UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorJohan Bidange, Johan Bidange UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorProf. Pierre H. Dixneuf, Prof. Pierre H. Dixneuf UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorDr. Cédric Fischmeister, Dr. Cédric Fischmeister UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorDr. Christian Bruneau, Corresponding Author Dr. Christian Bruneau [email protected] UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939UMR 6226 CNRS-Université de Rennes, Institut des Sciences Chimiques de Rennes, Organométalliques: Matériaux et Catalyse, Campus de Beaulieu, 35042, Rennes (France), Fax: (+33) 223236939Search for more papers by this authorDr. Jean-Luc Dubois, Dr. Jean-Luc Dubois ARKEMA, 420 Rue d'Estienne d'Orves, 92705 Colombes (France)Search for more papers by this authorDr. Jean-Luc Couturier, Dr. Jean-Luc Couturier ARKEMA, CRRA, BP, 63 Rue Henri Moissan, 69493, Pierre-Bénite (France)Search for more papers by this author First published: 24 October 2012 https://doi.org/10.1002/cctc.201200511Citations: 45Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Graphical Abstract Emphatic aliphatics: The catalytic reduction of alkyl nitriles into primary amines with ruthenium–benzylidene and ruthenium–indenylidene catalysts allowed the efficient hydrogenation of aliphatic nitrile esters that were derived from plant oils. References 1 1aD. Pingen, C. Müller, D. Vogt, Angew. Chem. 2010, 122, 8307; Angew. Chem. Int. Ed. 2010, 49, 8130; 1bS. Imm, S. Bähn, L. Neubert, H. Neumann, M. Beller, Angew. Chem. 2010, 122, 8303; Angew. Chem. Int. Ed. 2010, 49, 8126; 1cC. Gunanathan, D. Milstein, Angew. Chem. 2008, 120, 8789; Angew. Chem. Int. Ed. 2008, 47, 8661; 1dM. Hellin, F. Coussemant, FR1216263, 1960; 1eA. B. Brown, E. E. Reid, J. Phys. Chem. 1924, 28, 1067. 2D. W. Kim, C. E. Song, D. Y. Chi, J. Org. Chem. 2003, 68, 4281. 3 3aI. R. Baxendale, S. V. Ley, F. H. Sneddon, Synlett 2002, 0775; 3bC.-W. Kuo, J.-L. Zhu, J.-D. Wu, C.-M. Chu, C.-F. Yao, K.-S. Shia, Chem. Commun. 2007, 301. 4T. Beillon, J.-P. 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Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description cctc_201200511_sm_miscellaneous_information.pdf172.5 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume4, Issue12December 2012Pages 1911-1916 ReferencesRelatedInformation

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