Demonstration of the synthetic utility of the generation of alkoxy radicals by the photo-induced homolytic dissociation of alkyl 4-nitrobenzenesulfenates
1994; Elsevier BV; Volume: 35; Issue: 25 Linguagem: Inglês
10.1016/s0040-4039(00)73339-9
ISSN1873-3581
AutoresDaniel J. Pasto, François Cottard,
Tópico(s)Chemical Reaction Mechanisms
ResumoThe synthetic utility of the generation and study of the reactions of alkoxy radicals generated by the photo-induced, homolytic dissociation of alkyl 4-nitrobenzenesulfenates is demonstrated. The efficient formation of remotely substituted alcohol derivatives, and the addition of the alkoxy radical to a remotely situated CC is illustrated.
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