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An Open-Framework Thorium Sulfate Hydrate with 11.5 Å Voids

2008; American Chemical Society; Volume: 47; Issue: 20 Linguagem: Inglês

10.1021/ic800931f

1520-510X

Richard E. Wilson, S. Skanthakumar, Karah E. Knope, Christopher L. Cahill, L. Soderholm,

Nuclear materials and radiation effects

We report the synthesis of a thorium sulfate hydrate with 11.5 Å open channels that propagate through the structure. The compound crystallizes in the tetragonal space group P42/nmc, a = b = 25.890(4) Å, c = 9.080(2) Å, Z = 8, V = 6086.3(2) Å3. The thermal stability of the compound was investigated using thermogravimetric analysis and high-energy X-ray scattering (HEXS) revealing that the compound begins to undergo decomposition near 200 °C with an accompanied loss in crystallinity. The immediate coordination environment about the thorium atoms remains intact through heating to 500 °C as demonstrated by HEXS. Further heating reveals the formation of at least two crystalline phases, Th(SO4)2 and ThO2, which ultimately decompose to ThO2.